Ozone layer

The ozone layer is a layer in Earth's atmosphere which contains relatively high concentrations of ozone (O₃). This layer absorbs 97–99% of the Sun's high frequency ultraviolet light, which is damaging to life on Earth. It is mainly located in the lower portion of the stratosphere from approximately 13 to 40 kilometres (8.1 to 25 mi) above Earth, though the thickness varies seasonally and geographically. The ozone layer was discovered in 1913 by the French physicists Charles Fabry and Henri Buisson. Its properties were explored in detail by the British meteorologist G. M. B. Dobson, who developed a simple spectrophotometer (the Dobsonmeter) that could be used to measure stratospheric ozone from the ground. Between 1928 and 1958 Dobson established a worldwide network of ozone monitoring stations, which continue to operate to this day. The "Dobson unit", a convenient measure of the columnar density of ozone overhead, is named in his honor.

The photochemical mechanisms that give rise to the ozone layer were discovered by the British physicist Sidney Chapman in 1930. Ozone in the Earth's stratosphere is created by ultraviolet light striking oxygen molecules containing two oxygen atoms (O₂), splitting them into individual oxygen atoms (atomic oxygen); the atomic oxygen then combines with unbroken O₂ to create ozone, O₃. The ozone molecule is also unstable (although, in the stratosphere, long-lived) and when ultraviolet light hits ozone it splits into a molecule of O₂ and an atom of atomic oxygen, a continuing process called the ozone-oxygen cycle, thus creating an ozone layer in the stratosphere, the region from about 10 to 50 kilometres (33,000 to 160,000 ft) above Earth's surface. About 90% of the ozone in our atmosphere is contained in the stratosphere. Ozone concentrations are greatest between about 20 and 40 kilometres (12 and 25 mi), where they range from about 2 to 8 parts per million. If all of the ozone were compressed to the pressure of the air at sea level, it would be only a few millimeters thick.

Although the concentration of the ozone in the ozone layer is very small, it is vitally important to life because it absorbs biologically harmful ultraviolet (UV) radiation coming from the sun. UV radiation is divided into three categories, based on its wavelength; these are referred to as UV-A (400–315 nm), UV-B (315–280 nm), and UV-C (280–100 nm). UV-C, which would be very harmful to all living things, is entirely screened out by ozone at around 35 kilometres (115,000 ft) altitude. UV-B radiation can be harmful to the skin and is the main cause of sunburn; excessive exposure can also cause genetic damage, resulting in problems such as skin cancer. The ozone layer is very effective at screening out UV-B; for radiation with a wavelength of 290 nm, the intensity at the top of the atmosphere is 350 million times stronger than at the Earth's surface. Nevertheless, some UV-B reaches the surface. Most UV-A reaches the surface; this radiation is significantly less harmful, although it can potentially cause genetic damages.